| COMMENTS: | JPL-2010 recommendation, adopting the earlier recommendation of
S.P. Sander, R.R. Friedl, D.M. Golden, M.J. Kurylo, G.K. Moortgat, H. Keller-Rudek, P.H. Wine, A.R. Ravishankara, C.E. Kolb, M.J. Molina, B.J. Finlayson-Pitts, R.E. Huie, V.L. Orkin, “Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies. Evaluation Number 15“, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, 2006; http://jpldataeval.jpl.nasa.gov/ :
200-208 nm, mean of the data of F. Yao, I. Wilson, and H. Johnston, "Temperature-dependent ultraviolet absorption spectrum for dinitrogen pentoxide," J. Phys. Chem. 86, 3611-3615 (1982); DOI: 10.1021/j100215a023, and B.A. Osborne, G. Marston, L. Kaminski, N.C. Jones, J.M. Gingell, N. Mason, I.C. Walker, J. Delwiche, and M.-J. Hubin-Franskin, "Vacuum ultraviolet spectrum of dinitrogen pentoxide," J. Quant. Spectrosc. Radiat. Transfer 64, 67-74 (2000); DOI: 10.1016/S0022-4073(99)00104-1, 210-240 nm, mean of the data of F. Yao, I. Wilson, and H. Johnston, "Temperature-dependent ultraviolet absorption spectrum for dinitrogen pentoxide," J. Phys. Chem. 86, 3611-3615 (1982); DOI: 10.1021/j100215a023, B.A. Osborne, G. Marston, L. Kaminski, N.C. Jones, J.M. Gingell, N. Mason, I.C. Walker, J. Delwiche, and M.-J. Hubin-Franskin, "Vacuum ultraviolet spectrum of dinitrogen pentoxide," J. Quant. Spectrosc. Radiat. Transfer 64, 67-74 (2000); DOI: 10.1016/S0022-4073(99)00104-1 (two data sets), and M.H. Harwood, J.B. Burkholder, and A.R. Ravishankara, "Photodissociation of BrONO2 and N2O5: Quantum yields for NO3 production at 248, 308, and 352.5 nm," J. Phys. Chem. A 102, 1309-1317 (1998); DOI: 10.1021/jp9729829, 242-398 nm, data of M.H. Harwood, J.B. Burkholder, and A.R. Ravishankara, "Photodissociation of BrONO2 and N2O5: Quantum yields for NO3 production at 248, 308, and 352.5 nm," J. Phys. Chem. A 102, 1309-1317 (1998); DOI: 10.1021/jp9729829, 400-420 nm, data of M.H. Harwood, R.L. Jones, R.A. Cox, E. Lutman, and O.V. Rattigan, "Temperature-dependent absorption cross sections of N2O5," J. Photochem. Photobiol. A 73, 167-175 (1993); DOI: 10.1016/1010-6030(93)90001-2. Temperature coefficients for the parameterization log10 σ (cm2 molecule-1) = A + 1000B/T, valid over the range 233-295 K from M.H. Harwood, R.L. Jones, R.A. Cox, E. Lutman, and O.V. Rattigan, "Temperature-dependent absorption cross sections of N2O5," J. Photochem. Photobiol. A 73, 167-175 (1993); DOI: 10.1016/1010-6030(93)90001-2, ----------------------------------------------------------------
λ A B
(nm) (cm2 molec.-1) (cm2molec.-1 K-1)
----------------------------------------------------------------
260 -18.27 -0.091
270 -18.42 -0.104
280 -18.59 -0.112
290 -18.72 -0.135
300 -18.84 -0.170
310 -18.90 -0.226
320 -18.93 -0.294
330 -18.87 -0.388
340 -18.77 -0.492
350 -18.71 -0.583
360 -18.31 -0.770
370 -18.14 -0.885
380 -18.01 -0.992
390 -18.42 -0.949
400 -18.59 -0.966
410 -18.13 -1.160 |
